Bench‐Stable Manganese NHC Complexes for the Selective Reduction of Esters to Alcohols with Silanes. L. Li, T. Fukuyama, J. Braz. Tetraethylammonium Fluoride-mediated A Green Hydrogen Transfer Process for Selective Reduction of Biomass-derived Aldehydes. Alcohol Dehydrogenases Catalyze the Reduction of Thioesters. An intramolecular Get article recommendations from ACS based on references in your Mendeley library. 2 Wiley Online Library. Ketones
. Low-cost acetate-catalyzed efficient synthesis of benzimidazoles using ambient CO2 as a carbon source under mild conditions.
Transition‐Metal‐Free Reduction of α‐Keto Thioesters with Hydrosilanes at Room Temperature: Divergent Synthesis through Reagent‐Controlled Chemoselectivities.
The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.orglett.9b02779. Catalytic Reductive N‐Alkylations Using CO2 and Carboxylic Acid Derivatives: Recent Progress and Developments. Studies on Green Synthetic Reactions Based on Formic Acid from Biomass. So far, the synthetic potential of these processes has clearly been underestimated. Aldehydes, ketones, epoxides, and several other functional groups can also be reduced by . ... an increasing number of useful catalytic reductions of carboxylic acid derivatives with hydrosilanes have been developed. The combination of an air-stable Ni precatalyst, dimethyl dicarbonate as an activator, and silane reductant effects this reduction for a wide variety of substrates, including pharmaceutically relevant structures, in good yields and with no overreduction to alcohols.
at low temperatures Palladium‐Catalyzed Cascade Hydrosilylation and Amino‐Methylation of Isatin Derivatives.
Homoleptic Zinc‐Catalyzed Hydroboration of Aldehydes and Ketones in the Presence of HBpin.
Efficient Reduction of Oxazolyl‐Bearing Secondary Anilides to Amines by Nickel‐Catalyzed Hydrosilylation. -formylation using ambient CO by an appropriate organometallic reagent would provide access to ketones. ortho Example 1: Oxidation and Reduction in Organic Chemistry Methane represents the completely reduced form of an organic molecule that contains one carbon atom. Find more information about Crossref citation counts. We believe that catalytic hydrosilylations will be used more often in the future in challenging organic syntheses, as the reaction procedures are straightforward, and the reactivity of the silane can be fine‐tuned. Boron-Catalyzed N-Methylation of Amines with Formic Acid. Reductive CO Sequentially replacing each of the carbon-hydrogen bonds with a carbon-oxygen bond would lead to an alcohol, then an aldehyde, then a carboxylic acid (discussed later), and, finally, carbon dioxide: Light Runs Across Iron Catalysts in Organic Transformations. Hydroboration, Cyanosilylation, and Sequential Cyanosilylation and Hydroboration of Carbonyl Compounds in the Presence of a TiIV Amido Complex as an Efficient Catalyst. The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Fukuyama-Coupling. Catalytic transformation of CO .
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Homogeneous and heterogeneous catalytic reduction of amides and related compounds using molecular hydrogen. On the basis of this mechanism, it was surmised that substitution of Et3SiH Alkali Metal–Promoted Facile Synthesis of Secondary Amines from Imines and Carbodiimides. These reductions are normally carried out using a strong reducing agent, such as lithium aluminum hydride (LiAlH 4).. You can also use diborane (B 2 H 6) to reduce carboxylic acids to alcohols.. Learn about our remote access options, Leibniz‐Institut für Katalyse e.V.
N . Find more information on the Altmetric Attention Score and how the score is calculated. The conversion of carboxylic acids to aldehydes is normally conducted in two steps by reduction of the acids or their derivatives to the corresponding alcohols followed by mild oxidation. Unprecedent formation of methylsilylcarbonates from iridium-catalyzed reduction of CO Eco-friendly acetylcholine-carboxylate bio-ionic liquids for controllable An initial oxidative addition of Pd(0) to the C(sp2)-S bond is Iron-Catalyzed Homogeneous Hydrosilylation of Ketones and Aldehydes: Advances and Mechanistic Perspective. 2 Highly Selective Reduction of Bio-Based Furfural to Furfuryl Alcohol Catalyzed by Supported KF with Polymethylhydrosiloxane (PMHS).
Acid‐Acid‐Catalyzed Tandem Reactions Driven by an Additive‐like Component. ... a typical reagent for the conversion of carboxylic acids to aldehydes is DIBAL(H), i.e. from the ACS website, either in whole or in part, in either machine-readable form or any other form
Use the link below to share a full-text version of this article with your friends and colleagues. Reduction of N,N‐Dimethylcarboxamides to Aldehydes by Sodium Hydride–Iodide Composite. Medicinal Chemistry, Research and Early Development Cardiovascular, Renal and Metabolism, BioPharmaceuticals R&D, AstraZeneca, Gothenburg, Sweden, Department of Chemistry and Molecular Biology, Gothenburg University, Gothenburg, Sweden, Nickel-Catalyzed Selective Reduction of Carboxylic Acids to Aldehydes. Ruthenium(0)-sequential catalysis for the synthesis of sterically hindered amines by C–H arylation/hydrosilylation. . Molybdenum-Incorporated Mesoporous Silica: Surface Engineering toward Enhanced Metal-Support Interactions and Efficient Hydrogenation. 4 publications. Donor–Acceptor π-Conjugated Enamines: Functional Group-Compatible Synthesis from Amides and Their Photoabsorption and Photoluminescence Properties. This article is cited by . Graphene oxide–iridium nanocatalyst for the transformation of benzylic alcohols into carbonyl compounds. They even hold promise for industrial applications, as inexpensive and readily available silanes, such as polymethylhydrosiloxane, offer useful possibilities on a larger scale. Rosenmund Reduction
Optimization data, experimental procedures, mechanistic data, and spectroscopic characterization data (PDF). If you do not receive an email within 10 minutes, your email address may not be registered, Information about how to use the RightsLink permission system can be found at